【答案】:
C
【解析】:
A. $\because \sqrt{2}<\sqrt{3}$,$\therefore -\sqrt{2}>-\sqrt{3}$,故A錯誤;
B. $\frac{\sqrt{5}}{5}=\frac{1}{\sqrt{5}}$,$\frac{\sqrt{6}}{6}=\frac{1}{\sqrt{6}}$,$\because \sqrt{5}<\sqrt{6}$,$\therefore \frac{1}{\sqrt{5}}>\frac{1}{\sqrt{6}}$,$\therefore -\frac{\sqrt{5}}{5}<-\frac{\sqrt{6}}{6}$,故B錯誤;
C. $\because \pi\approx3.1416>3.14$,$\therefore -\pi<-3.14$,故C正確;
D. $\sqrt{10}\approx3.16>3$,$\therefore -\sqrt{10}<-3$,故D錯誤。
C