??$解:存在$??
??$因為正方形ABCD的邊長為4\ \mathrm {cm}$??
??$所以AD=CD=4\ \mathrm {cm},∠ADC= 90°$??
??$因為DF⊥DE$??
??$所以∠EDF=90°$??
??$所以∠ADE=∠CDF$??
??$①當\frac {AD}{CD}=\frac {DE}{DM}時, △ADE∽△CDM$??
??$因為AD=CD=4\ \mathrm {cm},DE=3\ \mathrm {cm}$??
??$所以\frac {4}{4}=\frac {3}{DM}$??
??$所以DM= 3\ \mathrm {cm}$??
??$②當\frac {AD}{DM}=\frac {DE}{CD}時,△ADE∽△CDM$??
??$因為AD=CD=4\ \mathrm {cm},DE= 3\ \mathrm {cm}$??
??$所以\frac {4}{DM}=\frac {3}{4}$??
??$所以DM =\frac {16}{3}\ \mathrm {cm}$??
??$綜上所述,存在點M使得以C、D、M為頂點的三角形與△ADE$??
??$相似,此時DM的長為3\ \mathrm {cm}或\frac {16}{3}\ \mathrm {cm}$??.